Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step
In aqueous TiO2 photocatalytic hydroxylation of weakly polar aromatics, a series of inverse H/D KIEs of 0.7–0.8 were observed, which is different than the normal H/D kinetic isotope effects (KIEs) usually observed for polar aromatics. This result indicated that the oxidation started by photo-induced hvb + can be the rate-determining step.
SUBSTITUTED ARYLOXYPROPYLAMINES WITH SEROTONINERGIC AND/OR NOREPINEPHRINERGIC ACTIVITY
Chemical syntheses and medical uses of novel inhibitors of the uptake of monoamine neurotransmitters and pharmaceutically acceptable salts thereof, for the treatment and/or management of psychotropic disorders, anxiety disorder, generalized anxiety disord
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Page/Page column 75
(2010/11/27)
Deuterium NMR spectroscopy is a versatile and economical tool for monitoring reaction kinetics in ionic liquids
Time-resolved 2H NMR spectroscopy is used to monitor the progress of and gain kinetic information for a variety of reactions in different ionic media.
Durazo, Armando,Abu-Omar, Mahdi M.
p. 66 - 67
(2007/10/03)
Kinetics of MTO-catalyzed oferin epoxidation in ambient temperature ionic liquids: UV/Vis and 2H NMR study
The kinetics of oxygen-atom transfer from the peroxo complexes of methyltrioxorhenium (MTO) to alkenes in ionic liquids have been investigated. Noncatalytic conversions of alkenes to epoxide were monitored by UV/Vis at 360 nm, where the monoperoxorhenium
Owens, Gregory S.,Durazo, Armando,Abu-Omar, Mahdi M.
p. 3053 - 3059
(2007/10/03)
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