Stereospecific trans-elimination of 2-alkoxy- and 2-cycloalkoxytropones to alkenes and cycloalkenes
The title compounds undergo thermal fragmentation to tropolones and alkenes and cycloalkenes.Product distribution and kinetic analyses of specifically labelled deuterio compounds establish the process to be a concerted electrocyclic reaction.
Takeshita, Hitoshi,Mametsuka, Hiroaki
p. 2035 - 2040
(2007/10/02)
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