- Copper-catalyzed C-H oxidation/cross-coupling of α-amino carbonyl compounds
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Keeping options open: The new and mild title reaction involving indoles selectively furnishes 1 and 2 with the aid of tert-butyl hydroperoxide (TBHP). The method represents the first example of a copper-catalyzed α arylation of α-amino carbonyl substrates leading to α-aryl α-imino and α-aryl α-oxo carbonyl compounds using a C-H oxidation strategy. Copyright
- Wu, Ji-Cheng,Song, Ren-Jie,Wang, Zhi-Qiang,Huang, Xiao-Cheng,Xie, Ye-Xiang,Li, Jin-Heng
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supporting information; experimental part
p. 3453 - 3457
(2012/06/01)
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- 1,3-DIPOLAR CYCLOADDITIONS OF C-BENZOYL-N-PHENYLNITRONE INDOLE DERIVATIVES
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Reaction of the title nitrone I with indole derivatives IIa,b gives the 1,3-addition product IIIa,b, its hydrogenated derivative IVa,b, and dehydrogenation products VIa,b and VIIa,b from transient product of 1,3-dipolar cycloaddition (V).Indole itself onl
- Fisera, Lubor,Mesko, Peter,Lesko, Jan,Dandarova, Miloslava,Kovac, Jaroslav,Goljer, Igor
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p. 1854 - 1863
(2007/10/02)
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