ADDITION OF TRIMETHYLSILYL CYANIDE TO α-SUBSTITUTED KETONES: CATALYSTEFFICIENCY
Addition of trimethylsilyl cyanide to α-substituted ketones is often slow and incomplete when catalyzed by zinc iodide.Use of potassium cyanide/18-crown-6 complex as catalyst is a superior method, providing high yields of adducts.
Greenlee, W. J.,Hangauer, D. G.
p. 4559 - 4560
(2007/10/02)
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