REACTIVITY OF THE 1-t.BUTYLTHIO-3-METHOXY-1-ALKENES TOWARDS METALATING AGENTS, II. ALLYLIC DEPROTONATION OF THE E-ISOMERS AND OF THE Z-PROPENYL DERIVATIVE.
Deprotonation of the title compounds with a lithiating agent and subsequent alkylation furnish the 1-substituted products 4.The 1-t.butylthio-3-methoxy-1-lithio-1-alkenes 3 become new equivalents of the hypothetical anions I.
Ruel, O.,Ekogha, C. Bibang Bi,Julia, S. A.
p. 4829 - 4832
(2007/10/02)
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