Reaction of Enamines with Dibenzylideneacetone - Solvent Effect and Electron Impact Study
The Stork addition of the pyrrolidineenamines of cycloalkanones (Ia-d) to dibenzylideneacetones (IIa-c) in ethanol media at room temperature, followed by heating briefly at reflux, results either in bis-adducts (IIIa-c) and/or bridged bicyclic diketones (IVa-c), which contain the rare bicyclodecane ring system.The proposed structures of the products have been fully corroborated by their mass fragmentation pattern.
Rao, T. Vedagiriswara,Anandan, Lalitha,Mathur, H. H.,Trivedi, G. K.
p. 864 - 867
(2007/10/02)
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