- New intermediate-spin chloroiron(III) complex with a mixed nitrogen-sulfur co-ordination sphere
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A new tetradentate proligand, 6,6′-bis(2,2-diphenyl-2-sulfanylethyl)-2,2′-bipyridine (H2L), involving two nitrogen bases and two thiols, has been synthesized. The crystal structure of its chloroiron(III) complex [FeL(Cl)] exhibits a five-co-ord
- Kopf, Marie-Aude,Varech, Daniel,Tuchagues, Jean-Pierre,Mansuy, Daniel,Artaud, Isabelle
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p. 991 - 998
(2007/10/03)
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- A Model for the Active Sites of Oxo-Transfer Molybdoenzymes: Synthesis, Structure, and Properties
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Development of models for the active sites of oxo-transfer molybdoenzymes has been initiated.Suitable models should be capable of oxygen atom transfer to or from the substrate, approach the native coordination unit, and be inert to formation of μ-oxo Mo(V
- Berg, Jeremy M.,Holm, R. H.
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p. 917 - 925
(2007/10/02)
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