A convenient method was developed for the synthesis of alkoxycyclopentadienes from the relatively easily obtainable 3-hydroxytricyclo2,6>deca-4,8-diene.It was shown that the obtained substances are equilibrium mixtures of isomers with respect to the position of the system of intracyclic double bonds and contain 1- and 2-substituted cyclopentadienes in a ratio 1:2 respectively.If the alkoxy group is removed from the cyclopentadiene ring, the ratio of the isomers (1:1.5) approximates to that for alkylcyclopentadienes.
Mironov, V. A.,Luk'yanov, V. T.,Bernadskii, A. A.
p. 61 - 70
(2007/10/02)
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