Investigation into factors influencing stereoselectivity in the reactions of heterocycles with donor-acceptor-substituted rhodium carbenoids
Rhodium-catalyzed decomposition of aryldiazoacetates in the presence of pyrroles or furans results in mono- or biscyclopropanation of the heterocycle, but with opposite enantioinduction, In the absence of sterically encumbering groups, the cyclopropanatio
Hedley, Simon J.,Ventura, Dominic L.,Dominiak, Paulina M.,Nygren, Cara L.,Davies, Huw M. L.