Facile synthesis of rhodium(III) porphyrin silyls by silicon-hydrogen bond activation with rhodium(III) porphyrin halides and methyls
Rhodium(III) porphyrin silyls were synthesized in high yields conveniently from the reactions of rhodium(III) porphyrin halides and methyls with silanes, via silicon-hydrogen bond activation (SiHA) in solvent-free conditions. Preliminary mechanistic exper
Zhang, Lirong,Chan, Kin Shing
p. 4822 - 4829
(2008/10/09)
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