Synthesis of Polynitro Compounds. Hexasubstituted Benzenes
The synthesis of the three isomeric aminotetranitrotoluenes by nitration of an appriopriate aminodinitrotoluene is presented, and the apparent ipso nitration of 4-amino-2,6-dinitrotoluene to give pentanitroaniline, is also discussed.The oxidation of the isomeric aminotetranitrotoluenes to pentanitrotoluene is described, as is the ammonolysis of pentanitroaniline and of pentanitrotoluene.
Atkins, Ronald L.,Hollins, Richard A.,Wilson, William S.
p. 3261 - 3266
(2007/10/02)
Methods of preparing pentanitrotoluene
Pentanitrotoluene is prepared by a method which comprises preparing an amdinitrotoluene from a precursor of either TNT or 2,5-dinitro-3-methylbenzoic acid, nitrating the aminodinitrotoluene to produce a nitramine intermediate, converting the nitramine intermediate to an aminotetranitrotoluene and oxidizing the aminotetranitrotoluene with peroxydisulfuric acid to pentanitrotoluene. Pentanitrotoluene is an explosive.
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(2008/06/13)
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