- An efficient method for phosphorylation of alcohols: Preparation of porphyrin-derived phosphates
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An effective method for the phosphorylation of phenols and various alcohols including porphyrins bearing hydroxyl groups was developed. The reaction of 6,7-bis(3-hydroxypropyl)-1,3,5,8-tetramethyl-2,4-divinylporphyrin with dialkyl chlorophosphate in the presence of DABCO as both a catalyst and a proton scavenger gave the desired phosphate in 97% yield.
- Pisarek, Sabina,Bednarski, Hubert,Gryko, Dorota
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p. 2667 - 2671,5
(2012/12/12)
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- An efficient method for phosphorylation of alcohols: Preparation of porphyrin-derived phosphates
-
An effective method for the phosphorylation of phenols and various alcohols including porphyrins bearing hydroxyl groups was developed. The reaction of 6,7-bis(3-hydroxypropyl)-1,3,5,8-tetramethyl-2,4-divinylporphyrin with dialkyl chlorophosphate in the presence of DABCO as both a catalyst and a proton scavenger gave the desired phosphate in 97% yield. Georg Thieme Verlag KG Stuttgart · New York.
- Pisarek, Sabina,Bednarski, Hubert,Gryko, Dorota
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p. 2667 - 2671
(2013/01/15)
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