(Z)-Narceine enol lactone (10) is thermodinamically less stable than its geometric isomer 11, and solvolyses faster in methanol to provide keto ester 9. In the less hindered hydrastine series, however, the order is reversed, and it is the E isomer 4 which
Blasko, Gabor,Shamma, Maurice
p. 1971 - 1974
(2007/10/02)
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