A manganese porphyrin-α-cyclodextrin conjugate as an artificial enzyme for the catalytic epoxidation of polybutadiene
We describe a manganese porphyrin-α-cyclodextrin conjugate as a catalyst for the epoxidation of cis-polybutadiene with trans-epoxide preference, which is a reverse stereoselectivity as compared to normal porphyrin catalysts. A clamp-like mechanism is prop
Zhang, Qi-Wei,Elemans, Johannes A. A. W.,White, Paul B.,Nolte, Roeland J. M.
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p. 5586 - 5589
(2018/06/04)
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