cas 96250-37-2, 2,2,3,3-TETRAFLUOROPROPYL 2-FLUOROACRYLATE | Articles data ｜lookchem

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96250-37-2

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OXYDATIVE NUCLEOPHILIC FLUORINATION OF C-Br BONDS. NEW PREPARATIVE APPLICATIONS
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Boguslavskaya, L. S.,Chuvatkin, N. N.
p. 138
(2007/10/02)

REACTIONS OF HALOGEN FLUORIDES XII. REACTION OF BROMINE TRIFLUORIDE WITH BROMINE-CONTAINING ESTERS. A NEW METHOD FOR THE SYNTHESIS OF FLUOROALKYL 2-FLUOROACRYLATES
Being weak Lewis bases, esters reduce the reactivity of bromine trifluoride in the substitutive fluorination of organic bromine derivatives.For this reason the rate of the reaction of bromine trifluoride with bromine-containing esters depends not only on the electronic characteristics of the substituents at the reaction center but also on the basicity of the ester.As a rule, the selectivity of the reaction increases with increase in the basicity of the ester.The reaction of bromine trifluoride or chlorine monofluoride with fluoroalkyl 2,3-dibromopropionates can be used successfully for the synthesis of monomers (fluoroalkyl 2-fluoroacrylates).
Kartashov, A. V.,Chuvatkin, N. N.,Boguslavskaya, L. S.
p. 2243 - 2248
(2007/10/02)

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Chemical Properties

Boiling Point: 145.1 °C at 760 mmHg
Flash Point:47.2 °C
Density: 1.328 g/cm³
Vapor Pressure: 4.93mmHg at 25°C
Refractive Index: 1.36
PSA: 26.30000
LogP: 1.91320

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