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CIS-Cypermethric Acid

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Name

CIS-Cypermethric Acid

EINECS 259-768-2
CAS No. 59042-49-8 Density 1.433 g/cm3
PSA 37.30000 LogP 2.66220
Solubility N/A Melting Point 83 - 85ºC
Formula C8H10 Cl2 O2 Boiling Point 290.6 °C at 760 mmHg
Molecular Weight 209.072 Flash Point 129.6 °C
Transport Information N/A Appearance Amorphous powder, white to off-white in colour
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 59042-49-8 (cis-DL-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid) Hazard Symbols N/A
Synonyms

Cyclopropanecarboxylicacid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, (1R,3R)-rel-;Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, cis-;cis-2,2-Dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylic acid;cis-3-(2,2-Dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid;cis-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropane-1-carboxylic acid;cis-DL-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid;cis-Permethric acid;

Article Data 22

CIS-Cypermethric Acid Synthetic route

64879-04-5

methyl cis-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
With potassium hydroxide In ethanol for 5h; Heating;100%
61976-30-5

methyl 2,2-dimethyl-3-(2,2-dichloroethenyl)cyclopropane-1-carboxylate

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
With sodium hydroxide In methanol at 40℃; for 8h;95%
95470-23-8

cis-3-<(2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropyl)carbonyl>-2-oxazolidinone

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran; ethanol Heating;62%
61949-76-6

3-phenoxybenzyl (1RS)-cis-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

A

53874-66-1

3-phenoxybenzyl chloride

59042-49-8

cis-permethrinic acid

C

13826-35-2

3-Phenoxybenzyl alcohol

3-phenoxybenzyl (1RS)-trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

Conditions
ConditionsYield
With potassium chlorate at 210℃; for 0.25h; Product distribution; Further Variations:; Reagents; Solvents; reaction time;A 3.7%
B 0.9%
C 3.3%
D n/a
61976-30-5

methyl 2,2-dimethyl-3-(2,2-dichloroethenyl)cyclopropane-1-carboxylate

59042-49-8

cis-permethrinic acid

methyl Z,cis-2,2-dimethyl-3-(2-chlorovinyl)cyclopropanecarboxylate

methyl E,cis-2,2-dimethyl-3-(2-chlorovinyl)cyclopropanecarboxylate

59897-93-7, 59897-94-8, 61898-95-1, 61976-30-5, 61976-31-6, 63805-74-3, 74561-29-8, 84984-65-6, 84984-66-7

methyl trans-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate

Conditions
ConditionsYield
In methanol Irradiation; Yield given. Further byproducts given;A n/a
B n/a
C n/a
D 2%
In methanol Irradiation; Further byproducts given;A n/a
B n/a
C n/a
D 2%
623-73-4

diazoacetic acid ethyl ester

55667-43-1

1,1-dichloro-4-methyl-penta-1,3-diene

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
With copper Erhitzen des Reaktionsprodukts mit Essigsaeure und wss. HCl;

cis-2-Chlor-3,3-dimethyl-4-(2',2',2'-trichloraethyl)cyclobutanon

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
With sodium hydroxide
59609-49-3

ethyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
With sodium hydroxide In methanol at 65℃; for 0.416667h; Product distribution; Rate constant; reactions for var. times;
With sodium hydroxide In ethanol; water at 100℃; for 5h; Yield given. Yields of byproduct given;
137547-99-0

(1S,3S)-3-(2,2-Dichloro-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid; compound with thiophene

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
at 100℃; under 1 Torr; for 4h;
at 80℃; under 10 Torr;

cis-2-Chlor-3,3-dimethyl-4-(2',2',2'-trichloraethyl)cyclobutanon

59042-49-8

cis-permethrinic acid

Conditions
ConditionsYield
With sodium hydroxide In water 1.) -7 deg C, 24 h; 2.) 100 deg C, 8 h;

CIS-Cypermethric Acid Specification

The CIS-Cypermethric Acid, with the CAS registry number 59042-49-8, is also known as cis-Permethric acid; cis-(Dichlorovinyl)dimethylcyclopropanecarboxylic acid; cis-DL-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid. It belongs to the product categories of Organic matters.This chemical's molecular formula is C8H10Cl2O2 and molecular weight is 209.07.What's more,Its systematic name is Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-,(1R,3R)-rel-.

Physical properties about CIS-Cypermethric Acid are:(1)ACD/LogP: 2.237; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.34; (4)ACD/LogD (pH 7.4): -0.47; (5)ACD/BCF (pH 5.5): 3.71; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 49.35; (8)ACD/KOC (pH 7.4): 1.00; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 2; (12)Index of Refraction: 1.6; (13)Molar Refractivity: 49.918 cm3; (14)Molar Volume: 145.853 cm3; (15)Surface Tension: 54.8569984436035 dyne/cm; (16)Density: 1.433 g/cm3; (17)Flash Point: 129.561 °C; (18)Enthalpy of Vaporization: 58.311 kJ/mol; (19)Boiling Point: 290.617 °C at 760 mmHg; (20)Vapour Pressure: 0.00100000004749745 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES:Cl/C(Cl)=C/[C@@H]1[C@H](C(=O)O)C1(C)C;
(2)Std. InChI:InChI=1S/C8H10Cl2O2/c1-8(2)4(3-5(9)10)6(8)7(11)12/h3-4,6H,1-2H3,(H,11,12)/t4-,6-/m1/s1;
(3)Std. InChIKey:LLMLSUSAKZVFOA-INEUFUBQSA-N.

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