- Boyland-Sims Oxidation
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Boyland-Sims Oxidation
E. Boyland et al., J. Chem. Soc. 1953, 3623; E. Boyland, P. Sims, ibid. 1954, 980.
Alkaline persulfate oxidation of aromatic amines to yield predominantly the o-amino aryl sulfates. Acid-catalyzed hydrolysis generates the o-hydroxy aryl amines:
Regioselectivity/mechanistic study: E. J. Behrman, J. Org. Chem. 57, 2266 (1992). Review: idem, Org. React. 35, 421-511 (1988). Cf. Elbs Persulfate Oxidation.
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