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 Purification of Ethyleneimine
  • Purification of Ethyleneimine
  • Redistd in an Ar or N2 atmosphere in a fume hood, and stored over KOH in sealed bottles in a refrigerator. Commercial imine (CAS NO. ) has been dried over sodium and distd from the metal through an efficient column before use. It is a weaker base than Me2NH (pK 10.87) but is caustic to the skin. It should not be inhaled, causes inflammation of the eyes, nose and throat and one may become sensitised. It is sol in H2O and has an ammoniacal smell and reacts with CO2. Pure Ethyleneimine is comparatively stable but polymerises in the presence of traces of H2O and is occasionally explosive in the presence of acids. CO2 is sufficiently acidic to cause polymerisation (forms linear polymers) which is not free radical promoted. It is stable in the presence of bases.

    The violet 2:1 Cu complex crystd from EtOH containing a few drops of Ethyleneimine and adding Et2O has m 142 °C(decomp). The picrate has m 142 °C. It has also been dried with BaO, and distd from sodium under nitrogen.


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