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Diethyl sulfide

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Name

Diethyl sulfide

EINECS 206-526-9
CAS No. 352-93-2 Density 0.831 g/cm3
PSA 25.30000 LogP 1.75940
Solubility Miscible with alcohol, ethanol and ether. Slightly miscible with carbon tetrachloride. Immiscible with water. Melting Point -100 °C(lit.)
Formula C4H10S Boiling Point 94.4 °C at 760 mmHg
Molecular Weight 90.1894 Flash Point 15°F
Transport Information UN 2375 3/PG 2 Appearance Colourless liquid
Safety 9-16-26-33-36 Risk Codes 11-38
Molecular Structure Molecular Structure of 352-93-2 (1,1'-Thiobisethane) Hazard Symbols FlammableF; IrritantXi
Synonyms

Ethyl sulfide(8CI);1,1'-Thiobisethane;3-Thiapentane;Diethyl sulfide;Diethylthioether;Ethyl monosulfide;Ethyl thioether;Ethylthioethane;NSC 75157;Thioethyl ether;

Article Data 164

Diethyl sulfide Consensus Reports

Reported in EPA TSCA Inventory.

Diethyl sulfide Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

Diethyl sulfide Specification

The Ethyl sulfide with CAS registry number of 352-93-2 is also known as Diethyl sulfide. The IUPAC name is Ethylsulfanylethane. It belongs to product categories of Sulfide Flavor. Its EINECS registry number is 206-526-9. In addition, the formula is C4H10S and the molecular weight is 90.19. This chemical is a colourless liquid and should be sealed in cool place.

Physical properties about Ethyl sulfide are: (1)ACD/LogP: 1.95; (2)ACD/LogD (pH 5.5): 1.95; (3)ACD/LogD (pH 7.4): 1.95; (4)ACD/BCF (pH 5.5): 17.86; (5)ACD/BCF (pH 7.4): 17.86; (6)ACD/KOC (pH 5.5): 274.03; (7)ACD/KOC (pH 7.4): 274.03; (8)Index of Refraction: 1.439; (9)Molar Refractivity: 28.57 cm3; (10)Molar Volume: 108.5 cm3; (11)Surface Tension: 24.6 dyne/cm; (12)Density: 0.831 g/cm3; (13)Enthalpy of Vaporization: 31.77 kJ/mol; (14)Boiling Point: 94.4 °C at 760 mmHg; (15)Vapour Pressure: 54.2 mmHg at 25 °C.

Preparation of Ethyl sulfide: it is prepared by reaction of crude ethylsulfide. Firstly, mercury chloride is added to ethanol, then crude ethylsulfide is put into the mixture. Secondly, generated complex is refined by recrystallization and added to hydrochloric acid. At last, product is obtained by heating, washing and drying.

Uses of Ethyl sulfide: it is used to produce triethylsulfoniuim ethylsulfate by reaction with sulfuric acid diethyl ester. The reaction occurs with solvent acetonitrile and other condition of heating for 2.5 hours. The yield is about 85%. Besides, it is also used as a solvent for anhydrous minerals and in plating baths for gold and silver.

Ethyl sulfide is used to produce triethylsulfoniuim ethylsulfate by reaction with sulfuric acid diethyl ester.

When you are using this chemical, please be cautious about it. As a chemical, it is irritating to skin and highly flammable. During using it, wear suitable protective clothing. After using it, keep container in a well-ventilated place away from sources of ignition. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges.

You can still convert the following datas into molecular structure:
1. Canonical SMILES: CCSCC
2. InChI: InChI=1S/C4H10S/c1-3-5-4-2/h3-4H2,1-2H3
3. InChIKey: LJSQFQKUNVCTIA-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC inhalation > 1850mg/m3/10 (1850mg/m3)   National Defense Research Committee, Office of Scientific Research and Development, Progress Report.Vol. NDCrc-132, Pg. Nov, 1942.

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