Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
Ethyl 3-bromopropionate |
EINECS | 208-724-0 |
CAS No. | 539-74-2 | Density | 1.417 g/cm3 |
PSA | 26.30000 | LogP | 1.33450 |
Solubility | Soluble in water, alcohol, chloroform, benzene. | Melting Point |
184-186 °C(Solv: water (7732-18-5)) |
Formula | C5H9BrO2 | Boiling Point | 179 °C at 760 mmHg |
Molecular Weight | 181.029 | Flash Point | 79.4 °C |
Transport Information | N/A | Appearance | clear colorless to pale yellow liquid |
Safety | 26-37/39 | Risk Codes | 36/37/38 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
Propionicacid, 3-bromo-, ethyl ester (6CI,7CI,8CI);2-Ethoxycarbonylethyl bromide;3-Bromopropanoic acid ethyl ester;3-Bromopropionic acid ethyl ester;Ethyl3-bromopropanoate;Ethyl 3-bromopropionate;Ethyl b-bromopropionate;NSC 21812;b-Bromopropionic acid ethyl ester; |
Article Data | 25 |
Conditions | Yield |
---|---|
With hydrogen bromide In diethyl ether at 0 - 5℃; for 12h; | 99% |
With diethyl ether; hydrogen bromide erst unter Eiskuehlung, zuletzt bei Raumtemperatur; | |
With hydrogen bromide | |
With hydrogen bromide; dibenzoyl peroxide In diethyl ether |
Conditions | Yield |
---|---|
With hydroquinone In ethanol at 20 - 55℃; for 2h; | 91% |
ethyl 3-chloropropanoate
A
Ethyl 3-bromopropionate
B
2-bromo-2’-chlorodiethyl ether
Conditions | Yield |
---|---|
With sodium bromide; 1,2-dibromomethane In N,N-dimethyl-formamide at 100℃; for 6h; | A 85% B n/a |
Conditions | Yield |
---|---|
With Acetyl bromide; 2,5-bis(1,1-dimethylethyl)-1,4-benzenediol at 20 - 50℃; for 2h; Overall yield = 11.6 g; | A n/a B 53.4% |
Conditions | Yield |
---|---|
With Acetyl bromide; hydroquinone; ethyl acrylate at 20 - 50℃; for 2h; Overall yield = 88.5 g; | A n/a B 53% |
methanol
ethyl acrylate
A
Ethyl 3-bromopropionate
B
Methyl 3-bromopropionate
Conditions | Yield |
---|---|
With Acetyl bromide; hydroquinone at 20 - 55℃; for 2h; Overall yield = 92.3 g; | A 51% B n/a |
Conditions | Yield |
---|---|
Zeitlicher Verlauf unter Belichtung; |
Conditions | Yield |
---|---|
With tetrachloromethane; phenol-2-sulfonic acid und entfernt das entstehende Wasser kontinuierlich mittels einer geeigneten Vorrichtung; | |
With tetrachloromethane; 5-sulfosalicylic Acid und entfernt das entstehende Wasser kontinuierlich mittels einer geeigneten Vorrichtung; | |
With sulfuric acid |
Conditions | Yield |
---|---|
durch Veresterung; |
Conditions | Yield |
---|---|
With hydrogen bromide at 2 - 5℃; |
Molecular structure of Propanoic acid,3-bromo-, ethyl ester (CAS NO.539-74-2) is:
Product Name: Propanoic acid,3-bromo-, ethyl ester
CAS Registry Number: 539-74-2
IUPAC Name: Ethyl 3-bromopropanoate
Molecular Weight: 181.02776 [g/mol]
Molecular Formula: C5H9BrO2
XLogP3-AA: 1.2
H-Bond Donor: 0
H-Bond Acceptor: 2
Refractive index: n20/D 1.452(lit.)
Sensitive: Light Sensitive
Surface Tension: 33.7 dyne/cm
Density: 1.417 g/cm3
Flash Point: 79.4 °C
Enthalpy of Vaporization: 41.53 kJ/mol
Boiling Point: 179 °C at 760 mmHg
Vapour Pressure: 0.962 mmHg at 25°C
EINECS: 208-724-0
Product Categories: Pharmaceutical Intermediates;C2 to C5;Carbonyl Compounds;Esters
Safty information about Propanoic acid,3-bromo-, ethyl ester (CAS NO.539-74-2) is:
Hazard Codes: Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39:Wear suitable gloves and eye/face protection.
WGK Germany: 3
Propanoic acid,3-bromo-, ethyl ester , its cas register number is 539-74-2. It also can be called Ethyl 3-bromopropanoate ; Ethyl 3-bromopropionate ; Ethyl beta-bromopropionate .It is a clear colorless to pale yellow liquid.