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Ethyl furfuryl ether

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Name

Ethyl furfuryl ether

EINECS 228-454-7
CAS No. 6270-56-0 Density 0.986 g/cm3
PSA 22.37000 LogP 1.81610
Solubility N/A Melting Point N/A
Formula C7H10O2 Boiling Point 136.5 °C at 760 mmHg
Molecular Weight 126.155 Flash Point 41.2 °C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 6270-56-0 (2-(ETHOXYMETHYL)FURAN) Hazard Symbols N/A
Synonyms

2-(Ethoxymethyl)furan;Ethyl furfuryl ether;Furfuryl ethyl ether;NSC 35558;

Article Data 27

Ethyl furfuryl ether Synthetic route

98-00-0

(2-furyl)methyl alcohol

64-17-5

ethanol

6270-56-0

2-(ethoxymethyl)furan

Conditions
ConditionsYield
With tin(IV) oxide at 200℃; for 20h; Temperature; Reagent/catalyst;95%
With arenesulfonic acid and phenyl groups functionalized ethane bridged organosilica nanohybrid at 120℃; for 0.5h; Reagent/catalyst; Autoclave;
With Zr-mesoporous silica (SBA-15) at 100℃; for 5h;
With niobium pentoxide nanowires calcined at 100 ∘C at 100℃; under 6000.6 Torr; for 5h;
98-00-0

(2-furyl)methyl alcohol

64-17-5

ethanol

A

6270-56-0

2-(ethoxymethyl)furan

B

1446756-00-8

4,5,5-triethoxypentan-2-one

C

539-88-8

4-oxopentanoic acid ethyl ester

Conditions
ConditionsYield
at 110℃; for 2h; Temperature; Reagent/catalyst; Autoclave; Ionic liquid;A n/a
B n/a
C 92%
With hydrothermally treated graphene oxide (GO-HT) at 120℃; for 6h; Autoclave;A 38.8%
B 11.7%
C 39.7%
98-00-0

(2-furyl)methyl alcohol

64-17-5

ethanol

A

6270-56-0

2-(ethoxymethyl)furan

B

539-88-8

4-oxopentanoic acid ethyl ester

Conditions
ConditionsYield
With sulfonic acid-functionalized MIL-101(Cr) at 140℃; for 2h; Temperature; Reagent/catalyst; Autoclave;A n/a
B 79.2%
With hierarchical-HZ-5 at 99.84℃; for 4h; Catalytic behavior; Green chemistry;A 26%
B 73%
With hierarchical-HZ-5 at 99.84℃; for 4h; Catalytic behavior; Green chemistry;A 49%
B 41%
13529-27-6

2-(diethoxymethyl)furan

A

98-01-1

furfural

B

6270-56-0

2-(ethoxymethyl)furan

C

614-99-3

Ethyl 2-furoate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In 1,2-dichloro-ethane at 0℃; for 0.25h;A 19%
B 54%
C 15%
With boron trifluoride diethyl etherate In 1,2-dichloro-ethane at 0℃; for 0.25h; Mechanism;A 19%
B 54%
C 15%
monoaluminum phosphate at 150℃; Product distribution; other catalysts ( γ-alumina, γ-aluminium sulphate), other temperatures, other (substituted) furaldehyde acetals;
98-00-0

(2-furyl)methyl alcohol

64-17-5

ethanol

A

6270-56-0

2-(ethoxymethyl)furan

B

13529-27-6

2-(diethoxymethyl)furan

C

539-88-8

4-oxopentanoic acid ethyl ester

Conditions
ConditionsYield
With silica-supported nickel phosphide at 180℃; under 750.075 Torr; for 3h; Temperature; Inert atmosphere; Autoclave;A 53.7%
B 7.4%
C 35.3%
98-00-0

(2-furyl)methyl alcohol

64-17-5

ethanol

A

6270-56-0

2-(ethoxymethyl)furan

B

1446756-00-8

4,5,5-triethoxypentan-2-one

Conditions
ConditionsYield
With graphene oxide at 80℃; for 6h; Autoclave;A 22.2%
B 12.3%
617-88-9

2-Chloromethylfuran

64-17-5

ethanol

6270-56-0

2-(ethoxymethyl)furan

Conditions
ConditionsYield
With potassium hydroxide; diethyl ether at 75 - 80℃;
117680-17-8

2-(Iodomethyl)tetrahydrofuran

64-17-5

ethanol

6270-56-0

2-(ethoxymethyl)furan

Conditions
ConditionsYield
With potassium hydroxide; diethyl ether
98-00-0

(2-furyl)methyl alcohol

75-03-6

ethyl iodide

6270-56-0

2-(ethoxymethyl)furan

Conditions
ConditionsYield
With potassium hydroxide
688-73-3

tri-n-butyl-tin hydride

81932-19-6

2-(furan-2-yl)-1,3-oxathiolane

A

6270-56-0

2-(ethoxymethyl)furan

B

127084-52-0

C19H36O2SSn

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In benzene Product distribution; Heating;

Ethyl furfuryl ether Specification

The Furan, 2-(ethoxymethyl)-, with the CAS registry number of 6270-56-0, is also known as Ethyl furfuryl ether. Its EINECS registry number is 228-454-7. This chemical's molecular formula is C7H10O2 and molecular weight is 126.15. What's more, its IUPAC name is 2-(Ethoxymethyl)furan.

Physical properties about Furan, 2-(ethoxymethyl)- are: (1)ACD/LogP: 1.65; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.65; (4)ACD/LogD (pH 7.4): 1.65; (5)ACD/BCF (pH 5.5): 10.56; (6)ACD/BCF (pH 7.4): 10.56; (7)ACD/KOC (pH 5.5): 188.15; (8)ACD/KOC (pH 7.4): 188.15; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 22.37 Å2; (13)Index of Refraction: 1.451; (14)Molar Refractivity: 34.47 cm3; (15)Molar Volume: 127.9 cm3; (16)Polarizability: 13.66×10-24 cm3; (17)Surface Tension: 29.1 dyne/cm; (18)Density: 0.986 g/cm3; (19)Flash Point: 41.2 °C; (20)Enthalpy of Vaporization: 35.85 kJ/mol; (21)Boiling Point: 136.5 °C at 760 mmHg; (22)Vapour Pressure: 9.11 mmHg at 25 °C.

Preparation: this chemical is prepared by Furfural-diethylacetal. The reaction needs reagent BF3O(C2H5)2 and solvent 1, 2-Dichloro-ethane. The reaction time is 15 minutes with reaction temperature of 0 °C. The yield is about 54 %.

Uses: it is used to produce other chemicals. For example, it is used to produce 5-Ethoxymethyl-furfuryl alcohol. This reaction needs reagent Acetic acid. Other condition of this reaction is reaction time of 3 hours at 70-80 °C. The yield is about 46 %.

You can still convert the following datas into molecular structure:
(1) SMILES: O(CC)Cc1occc1
(2) InChI: InChI=1/C7H10O2/c1-2-8-6-7-4-3-5-9-7/h3-5H,2,6H2,1H3
(3) InChIKey: BHGBNDNKYPEAAT-UHFFFAOYAB

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