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reaction mixture via centrifugation. The supernatant was then
analyzed by 1H NMR, revealing a 100% yield of cyclohexane.
ICPꢀMS analysis of the supernatant showed <0.1% leaching of
Co from the TiIII2TiIV6ꢀBDCꢀCoH catalyst.
ASSOCIATED CONTENT
Supporting Information. Synthesis and characterization of
Ti8ꢀBDCꢀCoCl, TiIII2TiIV6ꢀBDCꢀCoH, TiIV8ꢀBDCꢀCoH; Reacꢀ
tion procedures and product characterizations for catalytic
hydrogenation of arenes and heteroarenes; This material is
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AUTHOR INFORMATION
Corresponding Author
*wenbinlin@uchicago.edu
*xdp@imm.ac.cn
Author Contributions
The manuscript was written through contributions of all authors.
All authors have given approval to the final version of the manuꢀ
script.
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENT
This work was supported by National Science Foundation (CHEꢀ
1464941). Xꢀray absorption spectroscopy analysis was performed
at Beamline 9ꢀBM, supported by the Materials Research Collaboꢀ
rative Access Team (MRCAT). Use of the Advanced Photon
Source, an Office of Science User Facility operated for the U.S.
DOE Office of Science by ANL, was supported by the U.S. DOE
under Contract No. DEꢀAC02ꢀ06CH11357. We thank Guangxu
Lan for help with TEM and Dr. Alexander S. Filatov for help with
XPS.
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