Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 787 - 794 (1990)
Update date:2022-07-30
Topics:
Goryunov, E. I.
Petrovskii, P. V.
Shcherbina, T. M.
Laretina, A. P.
Zakharov, L. S.
Kabachnik, M. I.
The catalytic phosphorylation of α-polyfluoroalkylbenzyl alcohols by bis(polyfluoroalkyl) chlorophosphates is a convenient method for the synthesis of various bis(polyfluoroalkyl)(α-polyfluoroalkylbenzyl) phosphates, including those having donor substituents in the benzene ring.It was shown that in the series of p-methyl-α-trifluoromethylbenzyl phosphates p-CH3C6H4CH(CF3)OP(O)XY (where X, Y = Cl, CF3CH2O), the ability to act as O-alkylating agents with respect to polyfluorinated alcohols is a common characteristic, and the alkylating ability increases symbatically with increase in the overall electron-acceptor strength of the X and Y substituents at the phosphorus atom.
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