Tetrahedron p. 4025 - 4038 (1985)
Update date:2022-08-05
Topics:
Giese, Bernd
Horler, Hans
From aldehydes, ketones and esters β-carbonyl radicals 47 can be generated via enolization, cyclopropanation, solvomercuration and reduction with NaBH4.Radicals 47 react with electron-poor alkenes 27 to give products of CC-bond forming reactions (Tables 1-3).Carbonyl compounds are therefore precursors of three-carbon building blocks.The products result from reactions with "Umpolung".
View Morezhengzhou Triz Pharma-Tech Co., Ltd
website:http://www.Trizpharma-tech.com
Contact:+86-0371-86597269,53392065
Address:High-tech Industrial Development Zone, Zhengzhou City, NO.7 Holly Street
Hunan Dinuo Pharmaceutical Co.,Ltd.
Contact:86-731-88280100*8561
Address:Bio-pharmaceutical industrial park, Liuyang, Hunan, China
Feiyang Biotechnology Co., Ltd.
Contact:+86-533-7866339
Address:Qilu Chemistry Park, 200m north of Management Community Building of Park
Contact:+86-518-81061113
Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Guangzhou Reachin Chemical Co., Ltd
Contact:+86-20-37087379 ext.604
Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Doi:10.1039/b205614c
(2002)Doi:10.1021/jm00158a034
(1986)Doi:10.1016/S0040-4039(01)01468-X
(2001)Doi:10.1021/jo01349a523
(1966)Doi:10.1002/jlcr.1176
(2007)Doi:10.1016/j.tet.2004.05.024
(2004)