Journal of the American Chemical Society p. 7942 - 7947 (1987)
Update date:2022-08-02
Topics:
Mochida, Kunio
Wakasa, Masanobu
Sakaguchi, Yoshio
Hayashi, Hisaharu
Phenyl-substituted group 4B element-centered radicals generated by the direct photoejection from the group 4B element-centered anions were observed by laser photolysis at room temperature.In order to claify the mechanism of this process, CIDEP study of the photolysis of the group 4B element-centered anions was carried out at 77 and 4.2 K.From the emissive patterns observed for the germyl and stannyl anions after the excitation by a pluse laser, the photoejection reactions were most probably considered to occur from triplet anions.
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