Tetrahedron p. 5707 - 5710 (1985)
Update date:2022-08-04
Topics:
Devinsky, F.
Leitmanova, A.
Lacko, I.
Krasnec, L.
EDA-iodine complex with trialkylamine oxides in dichloromethane have been investigated spectrophotometrically.Thermodynamic (KADc,-ΔG0) and spectral (ΕADλ) characteristics of these complexes were determined.The absorption band of iodine in the visible region was blue-shifted with a variable maximum, depending on the structure of the amine oxide.The KADc and ΕADλ values were calculated using a modified method.A non-linear relationship KADc=<*>(R), where R is the number of carbon atoms in the alkyl chain, was found.
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