Journal of Fluorine Chemistry p. 79 - 87 (1990)
Update date:2022-08-03
Topics:
Schack, Carl J.
Christe, Karl O.
The low temperature reaction of TeF5OCl with the fluorocarbon iodides, CF3I, C2F5I, n-C3F7I, and i-C3F7I results in the formation of RfI(OTeF5)2 adducts.Except for the trifluoromethyl derivative these are stable, colorless compounds.The trifluoromethyl adduct decomposes above -78 deg C to give the previously unknown CF3OTeF5.The perfluoroethyl and n-propyl adducts decompose at 120 deg C or under UV radiation giving C2F5OTeF5 and n-C3F7OTeF5, respectively.These reactions constitute a new synthesis of primary RfOTeF5 compounds.Attempts to extend this synthesis to secondary fluorocarbon iodides were unsuccessful.
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Doi:10.1016/j.tet.2008.06.009
(2008)Doi:10.1055/s-1986-31846
(1986)Doi:10.1016/s0020-1693(98)00064-4
(1998)Doi:10.1016/S0040-4039(00)84359-2
(1986)Doi:10.1016/j.tetlet.2008.06.059
(2008)Doi:10.1016/S0040-4039(00)99344-4
(1989)