Journal of the Chemical Society. Chemical communications p. 1170 - 1171 (1986)
Update date:2022-09-26
Topics:
Kerschl, Susanna
Wrackmeyer, Bernd
The reaction of the system (E)-2-dimethyl(chloro)stannyl-3-diethylborylpent-2-ene (1)-LiNEt2 in hexane can be controlled to give 1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine (3) in high yield, demonstrating the imtermediacy of aminoborate (5) and the preference (under the reaction conditions) of intermolecular electrophilic attack at the B-C= bond accompanied by final elimination of LiCl and Et2NBEt2 (4).
View MoreContact:(86) 731 88718666
Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Contact:+86-134-5286-9121
Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
ZHONGBEI NORTHLAND BIO-CHEM INDUSTRY CO.,LTD
Contact:+86-452-6055586
Address:5F, C Liandalijing Bulding,No 259 Xinjiang Road, Jianhua District
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Alpha(shijiazhuang) Chemical Co., Ltd
Contact:+86-311-85652680
Address:Shijiazhuang City ,Hebei Province China
Doi:10.1039/jr9550000423
(1955)Doi:10.1246/bcsj.59.1629
(1986)Doi:10.1016/j.tetlet.2008.07.180
(2008)Doi:10.1055/s-2008-1078496
(2008)Doi:10.1021/jm00388a016
(1987)Doi:10.1016/S0040-4039(00)84677-8
(1986)