Journal of the Chemical Society, Dalton Transactions p. 1411 - 1418 (1986)
Update date:2022-08-05
Topics:
Jones, Michael D.
Kemmitt, Raymond D. W.
Platt, Andrew W. G.
1-<(Methylsulphonyloxy)methyl>-3-trimethylsilylprop-1-ene, available from 2-methylprop-2-en-1-ol, serves as a new entry into trimethylenemethane (tmm) metal complexes.Reaction with low-valent metal complexes affords the first tmm metal complexes of ruthenium, osmium, rhodium, and iridium:
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