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Supporting Information
Detailed experimental procedures and characterization of new
compounds are available free of charge via the Internet at
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AUTHOR INFORMATION
Corresponding Author
*Eꢀmail: tobisu@chem.eng.osakaꢀu.ac.jp;
chatani@chem.eng.osakaꢀu.ac.jp
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(9) Nickelꢀmediated decarbonylation of benzophenone having phosꢀ
phonite chelating groups: Obenhuber, A.; Ruhland, K. Organometallics
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Notes
The authors declare no competing financial interests.
(10) Selected reviews: (a) Li, B.ꢀJ.; Yu, D.ꢀG.; Sun, C.ꢀL. ; Shi, Z.ꢀJ.
Chem.–Eur. J. 2011, 17, 1728. (b) Cornella, J.; Zarate, C.; Martin, R.
Chem. Soc. Rev. 2014, 43, 8081. (c) Tasker, S. Z.; Standley, E. A.;
Jamison, T. F. Nature 2014, 509, 299. (d) Amii, H.; Uneyama, K. Chem.
Rev. 2009, 109, 2119. (e) Tobisu, M.; Chatani, N. Acc. Chem. Res. 2015,
48, 1717. (f) Ouyang, K.; Hao, W.; Zhang, W.ꢀX.; Xi, Z. Chem. Rev.
2015, 115, 12045. (g) Desnoyer, A. N.; Love, J. A. Chem. Soc. Rev. 2017,
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(11) Rhodiumꢀmediated oxidative addition of a CꢀC(=O) bond with the
aid of a directing group has been utilized in other catalytic transformation
of ketones. See ref 3. Foe recent examples: (a) Zeng, R.; Dong, G. J. Am.
Chem. Soc. 2015, 137, 1408. (b) Zeng, R.; Dong, G. J. Am. Chem. Soc.
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son, J. B. Org. Lett. 2016, 18, 3334. (d) Xia, Y.; Lu, G.; Liu, P.; Dong, G.
Nature 2016, 539, 546.
ACKNOWLEDGMENT
This work was supported by JSPS KAKENHI (15H03811) and
Scientific Research on Innovative Area "Precisely Designed Cataꢀ
lysts with Customized Scaffolding" (16H01022)from MEXT,
Japan. T.M. thanks the Program for Leading Graduate Schools:
“Interactive Materials Science Cadet Program.” for their support.
We also thank the Instrumental Analysis Center, Faculty of Engiꢀ
neering, Osaka University, for assistance with HRMS.
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