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reaction systems, all of the observed rate constants have the
values within the same range. This observation confirms the
statement that the kinetic observable, kobs, is predominantly
a consequence of the different types of phase transformation.
No correlations between the measured rate constants and the
molecular structure variation have been found.
(iv) Resemblance of the kinetics of the reactions in mechanical
mill with the kinetics of the thermal reactions in the freshly
sublimed crystals of monomers implies that the mechanisms
of two processes are similar. In both cases, the process is
triggered by formation of vacancies on the crystal surface.
The only difference is in the way the surface defects are
obtained, mechanically, or by sublimating away of monomer
molecules from the outer crystal plane. Slightly higher
reaction rates in mechanochemical systems are another ar-
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Acknowledgements
We gratefully acknowledge for the financial support to this work
from the Ministry of Science, Education, and Sports of the Republic
of Croatia, No. 119-1191342-1334. In addition, we thank Professor
Zlatko Mihalić for the helpful discussion and comments.
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