Journal of the American Chemical Society p. 900 - 911 (1988)
Update date:2022-07-30
Topics: Rearrangements Mechanistic Exploratory Diradical 1,2-Shift Photochemically 1,3-Diradical Organic Photochemistry
Zimmerman, Howard E.
Kamath, Ajit P.
The triplet photochemistry of 2,5-dianisyl-2,5-dimethyl-hex-3-ene was explored in a study of the behavior of diradical species occuring in the di-?-methane rearrangement.It was observed that the penultimate species, the 1,3-diradical, closes more rapidly
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