Chemistry Letters p. 1187 - 1190 (1987)
Update date:2022-08-04
Topics:
Ibata, Toshikazu
Isogami, Yasushi
Toyoda, Jiro
The reaction of aromatic chlorides, bromides and iodides with various primary or secondary amines in a tetrahydrofuran solution under high pressure of 6-12 kbar gave the corresponding secondary and tertiary aromatic amines. 1,4-Diazabicyclo<2.2.2>octane and quinuclidine gave N-aryl quaternary ammonium halides in high yields in contrast to the low reactivity of acyclic tertiary amines.
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(1987)