Chemistry of Heterocyclic Compounds p. 751 - 754 (1987)
Update date:2022-09-26
Topics: Formation of Products Formation of a Metal Acetylide Acetylenic Fragmentation
Prizhiyalgovskaya, N. M.
Kon'kov, L. I.
Tarshits, D. L.
Salmina, S. V.
Segizova, N. T.
Suvorov, N. N.
Indolenium salts, which readily undergo cleavage in aqueous alkali to give a monosubstituted acetylene and 1,3,3-trimethyl-2-oxindole, are formed when acyl derivatives of the Fischer base are heated with phosphorus oxychloride.Various aryl- and hetarylacetylenes can be conveniently obtained by this method.
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Doi:10.1039/DT9870001545
(1987)Doi:10.1016/S0040-4039(00)96088-X
(1987)Doi:10.1246/cl.1987.1267
(1987)Doi:10.1016/j.tet.2009.01.027
(2009)Doi:10.1007/BF00475375
(1987)Doi:10.1002/chem.200802349
(2009)