Journal of Organic Chemistry p. 1323 - 1328 (1990)
Update date:2022-07-29
Topics:
Gasparrini, Francesco
Giovannoli, Mario
Misiti, Domenico
Natile, Giovanni
Palmieri, Gianni
Tetrabromoaurate(III) is an efficient catalyst for the oxidation of sulfides to sulfoxides by nitric acid in a biphasic system (nitromethane/water).The system is selective and can be applied to the oxidation of any type of dialkyl and alkyl aryl sulfide and also of diaryl sulfides activated by electron-releasing substituents.The nature of the active species has been investigated in relation to the mechanistic aspects.
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