Synthetic Communications p. 1609 - 1616 (2011)
Update date:2022-09-26
Topics:
Yu, Jian-Jun
Wang, Li-Min
Guo, Feng-Lou
Liu, Jin-Qian
Liu, Ying
Jiao, Ning
A general, simple, and environmentally friendly method for the direct amination of secondary benzyl alcohols with amides or 4-nitroaniline is described. This method has been applied to a variety of substrates, and the reaction proceeded smoothly at room temperature under solvent-free conditions. CbzNH2 was proved to be very useful in the direct preparation of the benzylic amines from corresponding alcohols.
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