Journal of the American Chemical Society p. 4829 - 4837 (1989)
Update date:2022-08-03
Topics: Stereoselective synthesis Total synthesis Organic synthesis Protecting group Reaction Conditions Chiral Auxiliary Chemistry Structural Elucidation (±)-pancratistatin
Danishefsky
Lee
The total synthesis of the antitumor title compound has been accomplished. Among the key steps was an iodolactonization of a cyclohexadiene bearing a neighboring carboxamido group mediated by an ortho-stannylated phenol. A series of cis vicinal functional
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