[11] J. Zhang, C. Yu, S. Wang, et al., A novel and efficient methodology for the construction of quinazolines based on supported copper oxide
nanoparticles, Chem. Commun. 46 (2010) 5244-5246.
[12] Y. Yan, Z. Wang, Metal-free intramolecular oxidative decarboxylative amination of primary α-amino acids with product selectivity,
Chem. Commun. 47 (2011) 9513-9515.
[13] Y. Yan, Y. Zhang, C Feng, et al., Selective iodine-catalyzed intermolecular oxidative amination of C (sp3)-H bonds with ortho-carbonyl-
substituted anilines to give quinazolines, Angew. Chem. Int. Ed. 51 (2012) 8077-8081.
[14] R. Sarma, D. Prajapati, Microwave-promoted efficient synthesis of dihydroquinazolines, Green Chem. 13 (2011) 718-722.
[15] Z.H. Zhang, X.N. Zhang, L.P. Mo, et al., Catalyst-free synthesis of quinazoline derivatives using low melting sugar–urea–salt mixture as
a solvent, Green Chem. 14 (2012) 1502-1506.
[16] Z. Chen, J. Chen, M. Liu, et al., Unexpected copper-catalyzed cascade synthesis of quinazoline derivatives, J. Org. Chem. 78 (2013)
11342-11348.
[17] B. Han, C. Wang, R.F. Han, et al., Efficient aerobic oxidative synthesis of 2-aryl quinazolines via benzyl C–H bond amination catalyzed
by 4-hydroxy-TEMPO, Chem. Commun. 47 (2011) 7818-7820.
[18] X. Su, C. Chen, Y. Wang, et al. One-pot synthesis of quinazoline derivatives via [2+ 2+ 2] cascade annulation of diaryliodonium salts and
two nitriles. Chem. Commun. 49 (2013) 6752-6754.
[19] Y. Wang, X. Su, C. Chen, One-Pot synthesis of multiply substituted quinoline and quinazoline derivatives via [2+ 2+ 2] cascade
annulation with diaryliodonium salts, Synlett, 24 (2013) 2619-2623.
[20] D. Zhao, Q. Shen, J.-X. Li, Potassium iodide-catalyzed three-component synthesis of 2-arylquinazolines via amination of benzylic C- H
bonds of methylarenes, Adv. Synth. Catal. 357 (2015) 339-344.
[21] W.W. Sun, P. Cao, R.Q. Mei, et al., Palladium-catalyzed unactivated C (sp3)–H bond activation and intramolecular amination of
carboxamides: a new approach to β-lactams, Org. Lett. 16 (2013) 480-483.
[22] R. Xia, H.Y. Niu, G.R. Qu, et al., CuI controlled C–C and C–N bond formation of heteroaromatics through C (sp3)–H activation, Org.
Lett. 14 (2012) 5546-5549.
[23] H. Lu, Y. Hu, H. Jiang, et al., Stereoselective radical amination of electron-deficient C (sp3)–H bonds by Co (II)-based metalloradical
catalysis: direct synthesis of α-amino acid derivatives via α-C–H amination, Org. Lett. 14 (2012) 5158-5161.
[24] H.J. Kim, J. Kim, S.H. Cho, et al., Intermolecular oxidative C–N bond formation under metal-free conditions: control of chemoselectivity
between aryl sp2 and benzylic sp3 C–H bond imidation, J. Am. Chem. Soc. 133 (2011) 16382-16385.
[25] W.C. Gao, S. Jiang, R.L. Wang, et al., Iodine-mediated intramolecular amination of ketones: the synthesis of 2-acylindoles and 2-
acylindolines by tuning N-protecting groups, Chem. Commun. 49 (2013) 4890-4892.
[26] H.Y. Thu, W.Y. Yu, C.M. Che, Intermolecular amidation of unactivated sp2 and sp3 CH bonds via palladium-catalyzed cascade CH
activation/nitrene insertion, J. Am. Chem. Soc. 128 (2006) 9048-9049.
[27] E. T. Nadres, O. Daugulis, Heterocycle synthesis via direct C–H/N–H coupling, J. Am. Chem. Soc. 134 (2012) 7-10.
[28] T. Kang, Y. Kim, D. Lee, et al., Iridium-catalyzed intermolecular amidation of sp3 C–H bonds: late-stage functionalization of an
unactivated methyl group, J. Am. Chem. Soc. 136 (2014) 4141-4144.
[29] G. He, Y. Zhao, S. Zhang, et al., Highly efficient syntheses of azetidines, pyrrolidines, and indolines via palladium catalyzed
intramolecular amination of C (sp3)–H and C (sp2)–H bonds at γ and δ positions, J. Am. Chem. Soc. 134 (2012) 3-6.
[30] J.J Neumann, S. Rakshit, T. Dröge, et al. Palladium-katalysierte amidierung nichtaktivierter C (sp3)-H-bindungen: von anilinen zu
indolinen, Angewandte Chemie, Angew. Chem. Int. Ed. 121 (2009) 7024-7027.
[31] J. Pan, M. Suand, S.L. Buchwald, Palladium (0)-catalyzed intermolecular amination of unactivated C sp3-H bonds, Angew. Chem. Int. Ed.
50 (2011) 8647-8651.
[32] K.W. Fiori, J. Du Bois, Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights, J. Am. Chem.
Soc. 129 (2007) 562-568.
[33] C.G. Espino, J. Du Bois, A Rh-catalyzed C-H insertion reaction for the oxidative conversion of carbamates to oxazolidinones, Angew.
Chem. Int. Ed. 113 (2001) 618-620.
[34] X. Ye, Z. He, T. Ahmed, et al., 1, 2, 3-Triazoles as versatile directing group for selective sp2 and sp3 C–H activation: cyclization vs
substitution. Chem. Sci. 4 (2013) 3712-3716.
[35] Q. Zhang, K. Chen, W. Rao, et al., Stereoselective synthesis of chiral α-amino-β-lactams through palladium (II)-catalyzed sequential
monoarylation/amidation of C (sp3)-H bonds, Angew. Chem. Int. Ed. 52 (2013) 13588-13592.
[36] G. He, S.Y. Zhang, W.A. Nack, et al., Use of a readily removable auxiliary group for the synthesis of pyrrolidones by the palladium-
catalyzed intramolecular amination of unactivated γ C (sp3)-H bonds, Angew. Chem. Int. Ed. 52 (2013) 11124-11128.
[37] A. McNally, B. Haffemayer, B.S.L. Collins, et al., Palladium-catalysed CH activation of aliphatic amines to give strained nitrogen
heterocycles, Nature 510 (2014) 129-133.
[38] M. Yang, B. Su, Y. Wang, et al., Silver-catalysed direct amination of unactivated C–H bonds of functionalized molecules, Nat. Commun.
5 (2014) 4707-4712.
[39] C.P. Allen, T. Benkovics, A.K. Turek, et al., Oxaziridine-mediated intramolecular amination of sp3-hybridized C−H bonds, J. Am. Chem.
Soc. 131 (2009) 12560-12561.
[40] Q. Michaudel, D. Thevenet, P.S. Baran, Intermolecular Ritter-type C–H amination of unactivated sp3 carbons, J. Am. Chem. Soc. 134
(2012) 2547-2550.
[41] Q. Li, Y. Huang, T. Chen, et al., Copper-catalyzed aerobic oxidative amination of sp3 C–H bonds: efficient synthesis of 2-
hetarylquinazolin-4 (3 H)-ones, Org. Lett. 16 (2014) 3672-3675.
[42] B.L. Tran, B. Li, M. Driess, et al., Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes, J. Am. Chem. Soc.
136 (2014) 2555-2563.
[43] X. Wu, Y. Zhao, G. Zhang, et al., Copper-catalyzed site-selective intramolecular amidation of unactivated C (sp3)-H bonds, Angew.
Chem. Int. Ed. 53 (2014) 3706-3710.
[44] R. Xia, H.Y. Niu, G.R. Qu, et al., CuI controlled C–C and C–N bond formation of heteroaromatics through C (sp3)–H activation, Org.
Lett. 14 (2012) 5546-5549.
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