10.1002/asia.201800759
Chemistry - An Asian Journal
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8.0 Hz, 2H), 3.60 (t, J = 6.5 Hz, 2H), 2.93 (t, J = 7.0 Hz, 2H),
2.43 (s, 3H), 1.49 (ddd, J = 13.9, 9.9, 6.9 Hz, 4H), 1.35-1.27 (m,
4H); MS (ESI/TOF) m/z: Calcd. for C13H21NO3S [M]+ 271.12;
Found: 271.12.
W. H. Bernskoetter, Organometallics 2017, 36, 409-416; i) F. Schneck,
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tert-Butyl (4-hydroxybutyl)carbamate (27):[9c] 1H NMR (400
MHz, CDCl3) δ = 4.93 (s, 1H), 3.56 (s, 2H), 3.30 (s, 1H), 3.06 (s,
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tert-Butyl (5-hydroxypentyl)carbamate (28):[9c] 1H NMR (400
MHz, CDCl3) δ = 3.64 (s, 2H), 3.32 (d, J = 4.6 Hz, 1H), 3.12 (d, J
= 6.2 Hz, 2H), 2.37 (t, J = 6.3 Hz, 1H), 1.88-1.73 (m, 2H), 1.66-
1.56 (m, 2H), 1.52-1.48 (m, 2H), 1.43 (s, 9H); MS (ESI/TOF) m/z:
Calcd. for C10H21NO3 [M]+ 203.15; Found: 203.15.
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6-aminohexan-1-ol (29):[9c] 1H NMR (400 MHz, CDCl3) δ = 3.63
(t, J = 6.6 Hz, 2H), 2.68 (t, J = 6.9 Hz, 2H), 1.56 (dd, J = 13.6,
7.0 Hz, 2H), 1.48-1.42 (m, 2H), 1.39-1.33 (m, 4H); MS (ESI/TOF)
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7-aminoheptan-1-ol (30):[9c] 1H NMR (400 MHz, CDCl3) δ =
3.64 (t, J = 6.6 Hz, 2H), 2.68 (t, J = 7.0 Hz, 2H), 1.57 (dt, J =
13.6, 6.8 Hz, 4H), 1.50-1.34 (m, 6H); MS (ESI/TOF) m/z: Calcd.
for C7H17NO [M]+ 131.13; Found: 131.13.
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Financial support from the National Key R&D Program of China
(2016YFA0202902), the National Natural Science Foundation of
China (No. 21572036) and the Department of Chemistry, Fudan
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Conflict of interest
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Keywords: aminoalcohols• hydrogenation • lactams •
ruthenium-pincer complexes • weak base
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