ARTICLE
9 Boekelheide, V.; Weinstock, J. J Am Chem Soc 1952, 74,
maintained for 13 h. The reaction mixture was cooled,
diluted with CHCl3, filtered, acidified with acetic acid, and
precipitated into methanol to yield 0.95 g of crude tan poly-
mer: [g] ¼ 0.16 dL/g (CHCl3, 25 ꢀC); GPC (THF): Mn ¼ 4.9
660–663.
10 Gibson, H. W. J Heterocyclic Chem 1970, 7, 1169–1172.
11 (a) Anton, A.; Baird, B. R. Kirk-Othmer Encycl Chem Tech
2006, 19, 739–772; (b) Palmer, R. J. Kirk-Othmer Encycl Chem
Tech 2006, 19, 772–797; (c) Mathews, A. S.; Ha, C.-S. Curr
Trends Polym Sci 2006, 10, 69–76; (d) Bryant, R. G. Kirk-Othmer
Encycl Chem Tech 2006, 20, 264–296.
ꢀ
kDa, Mw ¼ 7.8 kDa; TGA, 5% wt. loss @ 454 C in air; DSC:
Tg ¼ 180 ꢀC and no Tm. FTIR (KBr): 1664.1 cmꢁ1 (C¼¼O),
1592.2 cmꢁ1, 1500.6 cmꢁ1 (C¼¼C), 1245.4 cmꢁ1 (CAOAC).
1H NMR (270 MHz, CDCl3): d 1.70, s, 6H, CH3; 6.90–7.09, m,
8H, o to O; 7.2–7.28, m, 4H, o to C¼¼O; 7.68, t (J ¼ 8), 2H,
H6; 7.80, t (J ¼ 8), 2H, H7; 7.92, d (J ¼ 8), 2H, H5; 8.04, s,
4H, o to C(CH3)2; 8.15, d (J ¼ 8), 2H, H8; 8.70, s, 2H, H3.
12 (a) Hoover, M. F. J Macromol Sci Chem 1970, 4, 1327–417;
(b) Vorchheimer, N. Encycl Polym Sci Eng 1987, 11, 489–507;
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The authors are grateful to the donors of the Petroleum
Research Fund, administered by the American Chemical Soci-
ety, for support of this research through grant 19625 AC7. Prof.
C. F. K. Hermann was supported by a PRF Summer Fellowship.
They extend their gratitude to Prof. Thomas C. Ward and his
students for GPC, DSC, and TGA determinations. They thank the
National Science Foundation for funds to purchase the Agilent
6220 Accurate Mass TOF LC/MS Spectrometer (CHE-
0722638).
13 (a) de Abajo, J.; de la Campa, J. G. Adv Polym Sci 1999,
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