9
Sanford, M. S. J. Am. Chem. Soc., 2009, 131, 3796-3797; (d)
129.9, 128.6, 127.3, 124.6, 123.1, 25.2. HRMS (ESI) m/z calcd
ACCEPTED MANUSCRIPT
for C15H1235ClNO2 [M+Na]+ 296.0449; found 296.0448.
Racowski, J. M.; Gary, J. B.; Sanford, M. S. Angew. Chem.Int.
Ed., 2012, 124, 3470-3479.
9. (a) Furuya, T.; Ritter, T. J. Am. Chem. Soc., 2008, 130, 10060-
10061; (b) Furuya, T.; Kaiser, H. M.; Ritter, T. Angew. Chem. Int.
Ed., 2008, 47, 5993-5996.
10. (a) Engle, K. M.; Mei, T.; Wang, X.; Yu, J.-Q. Angew. Chem. Int.
Ed., 2011, 50, 1478-1491; (b) Wang, X.; Mei, T.; Yu, J.-Q. J. Am.
Chem. Soc., 2009, 131, 7520-7521; (c) Mei, T.; Wang, X; Yu, J.-
Q. J. Am. Chem. Soc., 2009, 131, 10806-10807; (d) Wang, X.; Lu,
Y.; Dai, H.; Yu, J.-Q. J. Am. Chem. Soc., 2010, 132, 12203-12205.
11. Rosewall, C. F.; Sibbald, P. A.; Liskin, D. V.; Michael, F. E. J.
Am. Chem. Soc., 2009, 131, 9488-9489.
4.4.4 N-(2-(4-Chlorobenzoyl)phenyl)acetamide (7d)
Following the general procedure C, the reaction was stirred at
70 oC for 12 h. The desired amide 7d (38 mg, 70%) was isolated
as a white solid: Mp: 125-127 oC; 1H NMR (600 MHz, CDCl3) δ
10.69 (s, 1 H), 8.61 (d, J = 8.0 Hz, 1 H), 7.65 (d, J = 8.5 Hz, 2
H), 7.60-7.55 (m, 1 H), 7.50 (dd, J = 8.0, 1.5 Hz, 1H), 7.47 (d, J
= 8.5 Hz, 2 H), 7.12-7.07 (m, 1 H), 2.22 (s, 3 H). 13C NMR (151
MHz, CDCl3) δ 198.3, 169.2, 140.5, 139.0, 136.9, 134.5, 133.1,
131.3, 128.7, 123.1, 122.2, 121.7, 25.2. HRMS (ESI) m/z calcd
for C15H1235ClNO2 [M+Na]+ 296.0449; found 296.0449.
12. For transition metal-mediated ortho-directed C-H activations, see:
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4.4.5 N-(2-(4-Methoxybenzoyl)phenyl)acetamide (7e)
Following the general procedure C, the reaction was stirred at
70 oC for 16 h. The desired amide 7e (25 mg, 47%) was isolated
as a white solid: Mp: 119-121 oC; 1H NMR (600 MHz, CDCl3) δ
10.52 (s, 1 H), 8.56 (d, J = 8.5 Hz, 1 H), 7.74 (d, J =8.5, 2 H),
7.55 (m, 2 H), 7.12-7.06 (m, 1 H), 6.97 (d, J =8.5, 2 H), 3.89 (s, 3
H), 2.20 (s, 3 H). 13C NMR (151 MHz, CDCl3) δ 197.9, 169.0,
163.5, 139.9, 133.5, 132.7, 132.6, 131.0, 124.29, 122.1, 121.7,
113.7, 55.5, 25.2. HRMS (ESI) m/z calcd for C16H15NO3
[M+Na]+ 292.0944; found 292.0944.
Acknowledgments
The financial support from ‘‘973’’ Program (2015CB856500)
and the National Natural Science Foundation of China (Grant No.
21672159) are gratefully acknowledged.
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