Tetrahedron p. 3791 - 3802 (1999)
Update date:2022-08-06
Topics:
Forbes, Judith E.
Saicic, Radomir N.
Zard, Samir Z.
Irradiation with visible light of S-alkoxycarbonyl xanthates derived from various alcohols gives rise to alkoxycarbonyl radicals with bifurcate reactivity: loss of carbon dioxide leads to deoxygenated derivatives (i.e. alkyl xanthates) whereas intramolecular addition to a suitably located double bond produces lactones; these new reactions were applied to the total synthesis of (±)-cinnamolide and (±)-methylenolactocin.
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