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This work was supported by research funds provided by the
Ministerio de Ciencia e Innovación of the Spanish Government
(project CTQ2009-11027/BQU).
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Supplementary data
27. Smith, M. B.; March, J. March’s Advanced Organic Chemistry: Reactions, Mecha-
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references therein.
General Experimental. Analytical and spectroscopic data. 1H NMR
and 13C NMR spectra of N-Boc thiomicamine, 5a, 6a, 11, and 13.
Figure S1. Tables S1eS4. Cartesian coordinates for transition states:
TS-sn2-1b, TS-sn2-2b, TS-sn2-3b, TS-sn2-4b, TS1-I, TS2-I, TS3-I, TS1-
II, TS2-II, and TS3-II.. Supplementary data associated with this article
data include MOL files and InChiKeys of the most important com-
pounds described in this article.
28. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.;
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