Journal of Organometallic Chemistry p. 321 - 332 (1990)
Update date:2022-08-02
Topics:
Fajari, Lluis
Julia, Luis
Riera, Juan
Molins, Elies
Miravitlles, Carlos
The reactions of SiCl4 and GeCl4 (or(PhCl)3SiCl and (PhCl)3GeCl where PhCl denotes Cl5C6) with PhClMgCl give perchloro(2,2'-biphenylene)diphenyl-silane (2) and -germane (3), respectively.The structure of both strained compounds have been determined by X-ray crystallography of their benzene solvates.The photobromination of germane 3 with Br2 results in cleavage of one germanium-biphenylene bond to give the highly crowded bromo(2-(2'-bromooctachlorobiphenyl))bis(pentachlorophenyl)germane (4).
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