Journal of Organic Chemistry p. 4560 - 4564 (1990)
Update date:2022-08-05
Topics:
Satyamurthy, N.
Barrio, Jorge R.
Schmidt, Derrick G.
Kammerer, Craig
Bida, Gerald T.
Phelps, Michael E.
The acid-catalyzed thermal decompositions of a number of 1-aryl-3,3-dialkyltriazenes (1) in the presence of nucleophiles have been conducted with a view to understanding the underlying mechanisms of these reactions.These reactions parallel the corresponding diazonium ion reactions in that a heterolytic dediazoniation path competes with a homolytic route.The relative proportion of the products arising due to these two competing mechanisms depends upon (a) the electron-transfer efficiency of the nucleophile, (b) the redox potential of the aryl diazonium substrate, and (c) the reaction solvent.
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Doi:10.1016/S0020-1693(00)88016-0
(1990)Doi:10.1021/jm00171a002
(1990)Doi:10.1016/0223-5234(90)90022-U
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(2017)Doi:10.1515/HC.2010.16.2-3.79
(2010)Doi:10.1021/jm00172a016
(1990)