PHTHALOCYANINE AND PORPHYRIN COMPLEXES
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9. Green crystals; H NMR (500 MHz, CDCl3) δ = 0.02 (t, J = 6.4 Hz, 6H, CH3), 1.20 (t,
J = 7.4 Hz, 24H, CH3), 1.48 (bq, J = 6.4 Hz, CH2), 1.81 (sext, J = 7.4 Hz, 16H, CH2), 2.18
(quint, J = 7.4 Hz, 16H, CH2), 4.64, 4.68 (dt, J = 8.0, 7.4 Hz, 16H, CH2), 8.77 (bs, 8H, Ar-H);
13C NMR (126 MHz, CDCl3) δ 11.5, 14.1, 19.6, 29.7, 31.6, 69.5, 105.4, 124.31, 130.7, 135.5,
148.5, 150.8, 153.0; high-resolution (HR)-FAB-MS: Anal. Calcd. for C74H90Br2N8O8S2Ti =
1,488.4169, found m/z = 1,488.4187 (M+).
10. 7a: Black green powder: 1H NMR (400 MHz CDCl3) δ = 0.20 (t, J = 7.4 Hz, 6H, CH3), 1.64 (q,
J = 7.4 Hz, 4H, CH2), 7.74–7.85 (m, 12H, m,p-PhH), 8.16 (m, 4H, o-PhH), 8.25 (m, 4H, o-PhH),
9.05 (s, 8H, b); 13C NMR (126 MHz CDCl3) δ = 11.4, 29.6, 123.7, 125.5, 127.1, 127.2, 128.3,
132.6, 133.1, 134.7, 141.2, 148.8, 150.3; HR-FAB-MS: Anal. Calcd. for C54H38Br2N4S248Ti =
1,012.0384. Found: m/z = 1012.0384 (M+); Anal. Calcd. for C54H38Br2N4S2Ti: C, 63.92; H,
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3.77; N, 5.52%. Found: C, 63.46; H, 4.02; N, 5.15%; 7b: Black green powder: H NMR (400
MHz CDCl3) δ = 0.27 (t, J = 7.3 Hz, 6H, CH3), 1.80 (q, J = 7.3 Hz, 4H, CH2), 7.44–7.86 (m,
12H, m,p-PhH), 8.15 (d, J = 6.72 Hz, 4H, o-PhH), 8.29 (d, J = 6.72 Hz, 4H, o-PhH), 9.05 (s,
8H, b); 13C NMR (126 MHz CDCl3) δ = 11.6, 29.7, 124.2, 125.4, 127.1, 127.2, 128.3, 132.6,
133.0, 134.8, 138.0, 141.1, 149.3, 150.3; FAB-MS m/z = 1,108.0 [MH+].