10.1002/chem.201900951
Chemistry - A European Journal
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In summary, we demonstrated the direct nucleophilic selenolation
of a wide range of aryl iodides and bromides with alkyl, aryl and
thiophene selenolates under mild reaction conditions, enabled by a
robust and air-stable Pd(I) dimer catalyst. Experimental mechanistic
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Acknowledgements
We thank the RWTH Aachen and the European Research Council
(ERC-637993) for funding. Calculations were performed with
computing resources granted by JARA-HPC from RWTH Aachen
University under project ‘jara0091’.
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Conflict of interest
The authors declare no conflict of interests.
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Received:
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Keywords: selenolation
homogeneous catalysis
• • DFT calculation •
dinuclear Pd(I)
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