Helvetica Chimica Acta p. 460 - 467 (1990)
Update date:2022-08-04
Topics:
Stanchev, Stephan
Hesse, Manfred
Synthesis of two naturally occurring macrocyclic lactones is described. (-)-(R)-Phoracantholide I ((-)-1; Scheme 2) was synthesized by asymmetric and chemoselective reduction of the side-chain C=O group of (-)-4-(1-nitro-2-oxocyclohexyl)butan-2-one ((-)-6
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