Synthesis p. 502 - 504 (1990)
Update date:2022-08-03
Topics:
Shatzmiller, Shimon
Bahar, Eliezer
Bercovici, Sorin
Cohen, Alexander
Verdoorn, Gerhard
Addition of lithium salts of oxime O-ethers to aldehydes affords the thermodynamically unfavored β-hydroxy (Z)-O-alkyloximes.Oxidation of the hydroxy function with chromium trioxide/pyridine complex gives the β-keto O-alkyloximes.Facile alkylation of the 1,3-dicarbonyl analogs is possible via their sodium or lithium salts.
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(2016)Doi:10.1021/jo301156e
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