Journal of the American Oil Chemists' Society p. 1229 - 1237 (2011)
Update date:2022-08-05
Topics:
Zerkowski, Jonathan A.
Haas, Michael J.
This paper reports the synthesis of a series of novel compounds where carboxylic acids have been linked to a phenol through amidomethyl units. For instance, one, two, or three fatty acids have been selectively appended to the phenol in yields above 75%. The fatty acid used was oleic acid, which was subsequently epoxidized. Other functional groups, such as amino acids, can be incorporated in these compounds. Examples of monomers that are suitable for polymerization were also prepared: one acrylamide, one styrene derivative, and two types of AB2 diamino acids, all of which contain oleic units that are sites for epoxidation and crosslinking. Fatty acid aryl ethers were prepared using hydroxy fatty acids. These molecules are intended to serve as augmented analogues of epoxidized vegetable oil. Their amide groups should lead to intermolecular aggregation through hydrogen bonding, and the option to covalently include other functional groups may permit tuning of the macroscopic materials properties of films, coatings, or solids constructed from them.
View MoreContact:732.938.2777
Address:5012 Industrial Road Farmingdale, NJ 07727
Nantong LiKai Chemical Co.,Ltd
Contact:+86-513-89068669
Address:Jincheng Science Park
Contact:18669908765
Address:Zibo City, Shandong Province, P.R.China
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)
Contact:+86-21-54159691
Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
website:http://www.maisonchem.com.cn
Contact:0086-311-83833777
Address:Leitou industrial district, xinji, shijiazhuang city, hebei province,
Doi:10.1016/j.molstruc.2009.06.047
(2009)Doi:10.1021/jm901112f
(2009)Doi:10.1016/j.bmcl.2009.08.085
(2009)Doi:10.1016/j.jphotochem.2009.10.012
(2010)Doi:10.1016/S0040-4020(88)90030-0
(1988)Doi:10.1039/P19880002213
(1988)